27Al chemical shifts
Al(H2O)63+ = 0 ppm
All chemical shifts given in ppm!
Source: Bruker Almanac 2012
Type | chemical shift range |
---|---|
alkyls, hydrides and their adducts | 65 to 220 |
halides and AlX4– | -30 to 90 |
halide adducts with O- donor ligands | 85 to 105 |
halide adducts with P- donor ligands | 85 to 110 |
alkoxides and their adducts | 60 to 120 |
tetrahedral AlO4 coordination | 55 to 80 |
Octahedral AlO6 in hydrates, hydroxides, aluminates, zeolites | -15 to 10 |