Here you can find physical properties for some deuterated solvents:
- Acetic Acid-d4
- Acetone-d6
- Acetonitrile-d3
- Benzene-d6
- Chloroform-d1
- Cyclohexane-d12
- Deuterium oxide
- 1,2-Dichloroethane-d4
- Dichlormethane-d2
- Diethylether-d10
- Diethylene glycol dimethyl ether-d14 (diglyme-d14)
- 1,2-Dimethoxyethane-d10 (glyme-d10)
- Dimethylformamide-d7
- Dimethylsulfoxide-d6
- 1,4-Dioxane-d8
- Ethanol-d6
- Formic acid-d2
- Methanol-d4
- Methyl cyclohexane-d14
- Nitrobenzene-d5
- Nitromethane-d3
- 2-Propanol-d8
- Pyridine-d5
- Tetrachloroethane-d2
- Tetrahydrofurane-d8
- Toluene-d8
- Trifluoroacetic acid-d1
- 2,2,2-Trifluoroethanol-d3
Degree of Deuteration
Degree of deuteration [%] | 99 | 99.5 | 99.8 | 99.95 |
Remaining concentration of protons [mol/l] | 0.1 – 0.06 | 0.05 – 0.03 | 0.02 – 0.01 | 0.006 – 0.003 |
Advisable concentration of substance [mol/l] | 0.1 | 0.05 | 0.02 | 0.005 |
2 comments
Is there any effect of changing solvents on the result?. I’m working on methanolic algal extract and I intend using chloroform as solvent for NMR due to the unavailability of methanol at the moment. Will there be any negative effect on my result?.
Author
In general, chemical shifts are solvent dependent. The sign and the value of the change in chemical shifts can are different. Dependent from solvent and substance.