Dichloromethane-d2

NMR- data

[Picture] Chemical shift [ppm] (Multiplicity) Coupling constants [Hz]
1H 5.31 (3) 1J(C,D) 27.2
13C 53.7 (5) 2J(H,D) 1.1
 H2O/HOD- Shift  1.52

 

Physical data

Formula CD2Cl2
Molecular weight [g/mol] 86.95
Density (d420) 1.36
Melting point [°C] -97
Boiling point [°C] 39
Inflammation temperature [°C]
Refraction index (nD20) 1.4230
Dynamic viscosity (20°C) [mPa s] 0.43
Magnetic suszeptibility (20°C) -0.733 x 10^(-6)
Dielectrical constant 8.93
Dipole momentum [D] 1.5
Polarity [kJ/mol] 172.0
Donor strength [kJ/mol] 10.0

Common impurities

compoundprotonmultiplicity1H-shift [ppm]carbon13C-shift [ppm]
waterOHs1.52xx
acetic acidCH 3s2.06CH 320.91
CO175.85
acetoneCH 3s2.12CH 331
CO206.78
acetonitrileCH 3s1.97CH 32.03
CN116.92
benzeneCHs7.35CH128.68
t-butyl-alcoholCH 3s1.24CH 331.46
OHsC -CH 369.11
carbon dioxideCO 2125.26
carbon disulfideCS 2192.95
carbon tetrachlorideCCl 496.52
chloroformCHs7.32CH77.99
18-crown-6CH 2s3.59CH 270.47
cyclohexaneCH 2s1.44CH 227.38
1,2-dichloroethaneCH 2s3.76CH 244.35
dichloromethaneCH 2s5.33CH 254.24
diethyletherCH 3t1.15CH 315.44
CH 2q3.43CH 266.11
1,4-dioxaneCH 2s3.65CH 267.47
diglymeCH 2m3.57CH 272.25
CH 2m3.5CH 270.7
OCH 3s3.28OCH 358.95
DMECH 3s3.34CH 359.02
CH 2s3.49CH 272.24
dimethylformamideCHs7.91CH162.57
CH 3s2.88CH 336.56
CH 3s2.76CH 331.39
ethaneCH 3s0.85CH 36.91
ethyleneCH 2s5.4CH 2123.2
ethanolCH 3t1.19CH 318.69
CH 2q3.66CH 258.57
OHs1.33xx
ethylene glycolCH 2s3.66CH 264.08
ethyl acetateCH3COs2CH3CO21.15
CO171.24
C H2 CH3q4.08C H2 CH360.63
CH 2 C H 3t1.23CH 2 C H 314.37
H greaseCH 3m0,84-0,90xx
CH 2broad1.27CH 230.14
hexamethylbenzeneCH 3s2.2CH 316.71
C132.09
n-hexaneCH 3t0.89CH 314.28
CH 2m1.27CH 2 (2,5)23.07
CH 2 (3,4)32.01
HMDSOCH 3s0.07CH 31.96
HMPACH 3d2.6CH 336.99
hydrogenH 2s4.59xx
imidazoleCH(2)s7.63CH(2)135.76
CH(4,5)s7.07CH(4,5)122.16
methaneCH 4s0.21CH 4-4.33
methanolCH 3s3.42CH 350.45
OHs1.09xx
nitromethaneCH 3s4.31CH 363.03
n-pentaneCH 3t0.89CH 314.24
CH 2m1.3CH 2 (2,4)22.77
CH 2 (3)34.57
propaneCH 3t0.9CH 316.63
CH 2septett1.32CH 216.63
2-propanolCH 3d1.17CH 325.43
CHseptett3.97CH64.67
propyleneCH3d1.71CH319.47
CH 2 (1)m4.93CH 2115.7
CH 2 (2)m5.03xx
CHm5.84CH134.21
pyridineCH(2,6)m8.59CH(2,6)150.27
CH(3,5)m7.28CH(3,5)124.06
CH(4)m7.68CH(4)136.16
pyrroleNHbroad8.69xx
CH (2,5)m6.79CH (2,5)117.93
CH (3,4)m6.19CH (3,4)108.02
pyrrolidineCH 2 (2,5)m2.82CH 2 (2,5)47.02
CH 2 (3,4)m1.67CH 2 (3,4)25.83
silicon greaseCH 3s0.09CH 31.22
tetrahydrofuranCH 2 (2,5)m3.69CH 2 (2,5)68.16
CH 2 (3,4)m1.82CH 2 (3,4)25.98
TolueneCH 3s2.31CH 321.53
C(1)138.36
CH (2,4,6)m7.15CH (2,6)129.35
CH (3,5)m7.24CH (3,5)128.54
CH (4)125.62
triethylamineCH 3t0.99CH 312.12
CH 2q2.48CH 246.75
The table was taken from German. The comma is therefore the decimal point.
For example, 4.3 stands for the English 4.3.

Source:
NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist
Gregory R. Fulmer, Alexander J. M. Miller, Nathaniel H. Sherden, Hugo E. Gottlieb, Abraham Nudelman, Brian M. Stoltz, John E. Bercaw and Karen I. Goldberg
Organometallics, 2010, 29 (9), pp 2176–2179
DOI: 10.1021/om100106e

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