Important Silylated Compounds used as 1H Shift References

NameChemical FormulaAbbreviationMolecular weigthBoiling or Melting Point (°C)δ 1H ppm (rel. TMS)
TetramethylsilaneMe4SiTMS88.2BP=26.30
HexamethyldisilaneMe3Si-SiMe3HMDS146.4BP=112,30.037
HexamethyldisiloxaneMe3Si-O-SiMe3HMDSO162.4BP=1000.055
HexamethyldisilazaneMe3Si-NH-SiMe3HMDSA161.4BP=1250.042
3-(trimethylsilyl)propane sulfonic acid sodium saltMe3Si(CH2)3SO3NaTSPSA218.3MP=2000.015
4,4-dimethyl-4-silapentane sodium sulfonateDSS
3-(trimethylsilyl)propionic acid sodium saltTSP
4,4-dimethyl-4-silapentane sodium carboxylateMe3Si(CH2)2COONaDSC168.2MP>3000.000
3-(trimethylsilyl)2,2,3,3-tetradeuteropropionic acid sodium saltMe3Si(CD2)2COONaTSP-d4172.2MP>3000.000
OctamethylcyclotetrasiloxaneOCTS296.8BP=175
MP=16.8
0.085
1,1,3,3,5,5-hexakis-(trideuteromethyl)-1,3,5-trisilacyclohexaneCS-d18216.6BP=208-0.327
Tetrakis-(trimethylsilyl)-methane[Me3Si]4CTTSM304.8MP=3070.236
Source: Bruker Almanac 2012

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