2,2,2-Trifluoroethanol-d3

NMR- data
	Chemical shift [ppm] (Multiplicity)		Coupling constants [Hz]
	¹H	5.02 3.88 (4*3)	J(H,D)	2 (9)
	¹³C	126.3 (4) 61.5 (4*5)	J(C,D)	22

	H₂O/HOD SHift	5

Physical data
Formula	C₂D₃F₃
Molecular weight [g/mol]	87.06
Density (d₄²⁰)	1.42
Melting point [°C]	-44
Boiling point [°C]	77
Inflammation temperature [°C]
Refraction index (n_D²⁰)	1.30
Dynamic viscosity (20°C) [mPa s]
Magnetic suszeptibility (20°C)
Dielectrical constant
Dipole momentum [D]
Polarity [kJ/mol]
Donor strength [kJ/mol]

Common Impurities - 2,2,2-Trifluoroethanol-d3

compound	proton	multiplicity	1H-shift	carbon	13C-shift
water	OH	s	3.66
acetic acid	CH 3	s	2.06	CH 3	20.91
				CO	177.96
acetone	CH 3	s	2.19	CH 3	32.35
				CO	214.98
acetonitrile	CH 3	s	1.95	CH 3	1
				CN	118.95
benzene	CH	s	7.36	CH	129.84
t-butyl-alcohol	CH 3	s	1.28	CH 3	31.07
	OH	s	2.2	C -CH 3	72.35
carbon dioxide				CO 2	126.92
carbon disulfide				CS 2	196.26
carbon tetrachloride				CCl 4	97.74
chloroform	CH	s	7.33	CH	78.83
18-crown-6	CH 2	s	3.64	CH 2	70.8
cyclohexane	CH 2	s	1.47	CH 2	28.34
1,2-dichloroethane	CH 2	s	3.71	CH 2	45.28
dichloromethane	CH 2	s	5.24	CH 2	54.46
diethylether	CH 3	t	1.2	CH 3	15.33
	CH 2	q	3.58	CH 2	67.55
diglyme	CH 2	m	3.67	CH 2	73.05
	CH 2	m	3.62	CH 2	71.33
	OCH 3	s	3.41	OCH 3	59.4
dimethylformamide	CH	s	7.86	CH	166.01
	CH 3	s	2.98	CH 3	37.76
	CH 3	s	2.88	CH 3	30.96
1,4-dioxane	CH 2	s	3.76	CH 2	68.52
DME	CH 3	s	3.4	CH 3	59.52
	CH 2	s	3.61	CH 2	72.87
ethane	CH 3	s	0.85	CH 3	7.01
ethanol	CH 3	t	1.22	CH 3	18.11
	CH 2	q	3.71	CH 2	59.68
	OH	s		x	x
ethyl acetate	CH3CO	s	2.03	CH3CO	21.18
				CO	175.55
	C H2 CH3	q	4.14	C H2 CH3	62.7
	CH 2 C H 3	t	1.26	CH 2 C H 3	14.36
ethylene	CH 2	s	5.4	CH 2	124.08
ethylene glycol	CH 2	s	3.72	CH 2	64.87
H grease	CH 3	m	0,88-0,94	x	x
	CH 2	broad	1.33	CH 2	x
hexamethylbenzene	CH 3	s	2.24	CH 3	17.04
				C	134.04
n-hexane	CH 3	t	0.91	CH 3	14.63
	CH 2	m	1.31	CH 2 (2,5)	24.06
				CH 2 (3,4)	33.17
HMDSO	CH 3	s	0.08	CH 3	2.09
HMPA	CH 3	d	2.63	CH 3	37.21
hydrogen	H 2	s	4.53	x	x
imidazole	CH(2)	s	7.61	CH(2)	136.58
	CH(4,5)	s	7.03	CH(4,5)	122.93
methane	CH 4	s	0.18	CH 4	-5.88
methanol	CH 3	s	3.44	CH 3	50.67
	OH	s		x	x
nitromethane	CH 3	s	4.28	CH 3	63.17
n-pentane	CH 3	t	0.9	CH 3	14.54
	CH 2	m	1.33	CH 2 (2,4)	23.75
				CH 2 (3)	35.76
propane	CH 3	t	0.9	CH 3	16.93
	CH 2	septett	1.33	CH 2	17.46
2-propanol	CH 3	d	1.2	CH 3	25.21
	CH	septett	4.05	CH	66.69
propylene	CH3	d	1.7	CH3	19.63
	CH 2 (1)	m	4.93	CH 2	116.38
	CH 2 (2)	m	5.03	x	x
	CH	m	5.87	CH	136
pyridine	CH(2,6)	m	8.45	CH(2,6)	149.76
	CH(3,5)	m	7.4	CH(3,5)	126.27
	CH(4)	m	7.82	CH(4)	139.62
pyrrole	NH	broad		x	x
	CH (2,5)	m	6.84	CH (2,5)	119.61
	CH (3,4)	m	6.24	CH (3,4)	108.85
pyrrolidine	CH 2 (2,5)	m	3.11	CH 2 (2,5)	47.43
	CH 2 (3,4)	m	1.93	CH 2 (3,4)	25.73
silicon grease	CH 3	s	0.16	CH 3	2.87
tetrahydrofuran	CH 2 (2,5)	m	3.78	CH 2 (2,5)	69.53
	CH 2 (3,4)	m	1.91	CH 2 (3,4)	26.69
Toluene	CH 3	s	2.33	CH 3	21.62
				C(1)	139.92
	CH (2,4,6)	m	7,1-7,3	CH (2,6)	130.58
	CH (3,5)	m	7,1-7,3	CH (3,5)	129.79
				CH (4)	126.82
triethylamine	CH 3	t	1.31	CH 3	9.51
	CH 2	q	3.12	CH 2	48.45

The table was taken from German. The comma is therefore the decimal point.
For example, 4.3 stands for the English 4.3.

Source:
NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist
Gregory R. Fulmer, Alexander J. M. Miller, Nathaniel H. Sherden, Hugo E. Gottlieb, Abraham Nudelman, Brian M. Stoltz, John E. Bercaw and Karen I. Goldberg
Organometallics, 2010, 29 (9), pp 2176–2179
DOI: 10.1021/om100106e

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2,2,2-Trifluoroethanol-d3

NMR- data

Physical data

Common Impurities - 2,2,2-Trifluoroethanol-d3

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