NMR- Data
| Isotope | 31P | Natural abundance (%) | 100 |
| Spin | 1/2 | Magnetic moment μ/μN | 1.95999 |
| Magnetogyric ratio γ/107rad s-1T-1 |
10.8394 | Frequency ratio Ξ/% |
40.480742 |
| Reference Compound | H3PO4 | Sample conditions | |
| receptivity relative to 1H | 6.65*10-2 | receptivity relative to 13C | 3.91*102 |
| Larmor Frequenzies (MHZ) vs. Bruker Field Strengths (Tesla) | |||
|---|---|---|---|
| 7.04925 | 9.39798 | 11.7467 | 14.0954 |
| 121.495 | 161.976 | 202.457 | 242.938 |
| 16.4442 | 17.6185 | 18.7929 | 19.9673 |
| 283.419 | 303.659 | 323.900 | 344.140 |
| 21.1416 | 22.3160 | 23.4904 | |
| 364.380 | 384.621 | 404.861 | |
| Phosphorus (III) compounds | |||
|---|---|---|---|
| δ / ppm | δ /ppm | ||
| PMe3 | -62 | PMeF2 | 245 |
| PEt3 | -20 | PMeH2 | -163.5 |
| P(n-Pr)3 | -33 | PMeCl2 | 192 |
| P(i-Pr)3 | -19.4 | PMeBr2 | 184 |
| P(n-Bu)3 | -32.5 | PMe2F | 186 |
| P(i-Bu)3 | -45.3 | PMe2H | -99 |
| P(s-Bu)3 | 7.9 | PMe2Cl | 96.5 |
| P(t-Bu)3 | 63 | PMe2Br | 90.5 |
| Phosphorous (V) compounds | |||
| Me3PO | 36.2 | Me3PS | 59.1 |
| Et3PO | 48.3 | Et3PS | 54.5 |
| [Me4P]+ | 24.4 | [Et 4P]+ | 40.1 |
| [PO4]3- | 6.0 | [PS]3- | 87 |
| PF5 | -80.3 | [PF6]- | -145 |
| PCl5 | -80 | [PCl4]+ | 86 |
| MePF4 | -29.9 | [PCl6]- | -295 |
| Me3PF2 | -158 | Me2PF3 | 8.0 |
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