{"id":49,"date":"2013-11-06T22:07:20","date_gmt":"2013-11-06T20:07:20","guid":{"rendered":"https:\/\/wissen.science-and-fun.de\/chemistry\/?p=49"},"modified":"2019-01-20T18:51:58","modified_gmt":"2019-01-20T16:51:58","slug":"toluene-d8","status":"publish","type":"post","link":"https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/","title":{"rendered":"Toluene-d8"},"content":{"rendered":"\n\n\n\n\n\n\n\n\n\n
\n

NMR- data<\/h3>\n<\/td>\n<\/tr>\n

\"[Picture]\"<\/td>\nChemical shift [ppm] (Multiplicity)<\/td>\nCoupling constants [Hz]<\/td>\n<\/td>\n<\/tr>\n
1<\/sup>H<\/td>\n2.09 (5)<\/td>\n1<\/sup>J(C,D)<\/td>\n22.0 (CD3<\/sub>)<\/td>\n<\/tr>\n
6.97 (H-1) (m)<\/td>\n24.0 (C-2,C-3)<\/td>\n<\/tr>\n
7.09 (H-2) (m)<\/td>\n19.0 (C-4)<\/td>\n<\/tr>\n
7.01 (H-3)<\/td>\n2<\/sup>J(H,D)<\/td>\n2.2<\/td>\n<\/tr>\n
13<\/sup>C<\/td>\n20.4 (7)
\n125.49 (3)
\n128.33 (3)
\n129.24 (3)
\n137.86<\/td>\n		3<\/sup>J(H,D)<\/td>\n1.2 (H-1)<\/td>\n<\/tr>\n
 H2<\/sub>O\/HOD Shift<\/td>\n 0.45<\/td>\n1.1 (H-2,H-3)<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

 
\n<\/p>\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
\n

Physical data<\/h3>\n<\/td>\n<\/tr>\n

Formula<\/td>\nC7<\/sub>D8<\/sub><\/td>\n<\/tr>\n
Molecular weight [g\/mol]<\/td>\n100.19<\/td>\n<\/tr>\n
Density (d4<\/sub>20<\/sup>)<\/td>\n0.94<\/td>\n<\/tr>\n
Melting point [\u00b0C]<\/td>\n-84.5<\/td>\n<\/tr>\n
Boiling point [\u00b0C]<\/td>\n109<\/td>\n<\/tr>\n
Inflammation temperature [\u00b0C]<\/td>\n4<\/td>\n<\/tr>\n
Refraction index (nD<\/sub>20<\/sup>)<\/td>\n1.4940<\/td>\n<\/tr>\n
Dynamic viscosity (20\u00b0C) [mPa s]<\/td>\n0.58<\/td>\n<\/tr>\n
Magnetic suszeptibility (20\u00b0C)<\/td>\n-0.6179 x 10-6<\/sup><\/td>\n<\/tr>\n
Dielectrical constant<\/td>\n2.4<\/td>\n<\/tr>\n
Dipole momentum [D]<\/td>\n0.4<\/td>\n<\/tr>\n
Polarity [kJ\/mol]<\/td>\n141.9<\/td>\n<\/tr>\n
Donor strength [kJ\/mol]<\/td>\n–<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n\n\n

Common impurities<\/h3>\n\n\n\n\n\n\n\t\n\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t
compound<\/th>proton<\/th>multiplicity<\/th>1H-shift<\/th>carbon<\/th>13C-shift<\/th>\n<\/tr>\n<\/thead>\n
water<\/td>OH<\/td>s<\/td>0.43<\/td><\/td><\/td>\n<\/tr>\n
acetic acid<\/td>CH 3<\/td>s<\/td>1.57<\/td>CH 3<\/td>20.27<\/td>\n<\/tr>\n
<\/td><\/td><\/td>CO<\/td>175.3<\/td>\n<\/tr>\n
acetone<\/td>CH 3<\/td>s<\/td>1.57<\/td>CH 3<\/td>30.03<\/td>\n<\/tr>\n
<\/td><\/td><\/td>CO<\/td>204<\/td>\n<\/tr>\n
acetonitrile<\/td>CH 3<\/td>s<\/td>0.69<\/td>CH 3<\/td>0.03<\/td>\n<\/tr>\n
<\/td><\/td><\/td>CN<\/td>115.76<\/td>\n<\/tr>\n
benzene<\/td>CH<\/td>s<\/td>7.12<\/td>CH<\/td>128.57<\/td>\n<\/tr>\n
t-butyl-alcohol<\/td>CH 3<\/td>s<\/td>1.03<\/td>CH 3<\/td>30.49<\/td>\n<\/tr>\n
OH<\/td>s<\/td>0.58<\/td>C -CH 3<\/td>68.12<\/td>\n<\/tr>\n
carbon dioxide<\/td><\/td><\/td><\/td>CO 2<\/td>124.86<\/td>\n<\/tr>\n
carbon disulfide<\/td><\/td><\/td><\/td>CS 2<\/td>192.71<\/td>\n<\/tr>\n
carbon tetrachloride<\/td><\/td><\/td><\/td>CCl 4<\/td>96.57<\/td>\n<\/tr>\n
chloroform<\/td>CH<\/td>s<\/td>6.1<\/td>CH<\/td>77.89<\/td>\n<\/tr>\n
18-crown-6<\/td>CH 2<\/td>s<\/td>3.36<\/td>CH 2<\/td>70.86<\/td>\n<\/tr>\n
cyclohexane<\/td>CH 2<\/td>s<\/td>1.4<\/td>CH 2<\/td>27.31<\/td>\n<\/tr>\n
1,2-dichloroethane<\/td>CH 2<\/td>s<\/td>2.91<\/td>CH 2<\/td>43.4<\/td>\n<\/tr>\n
dichloromethane<\/td>CH 2<\/td>s<\/td>4.32<\/td>CH 2<\/td>53.47<\/td>\n<\/tr>\n
diethylether<\/td>CH 3<\/td>t<\/td>1.1<\/td>CH 3<\/td>15.47<\/td>\n<\/tr>\n
CH 2<\/td>q<\/td>3.25<\/td>CH 2<\/td>65.94<\/td>\n<\/tr>\n
1,4-dioxane<\/td>CH 2<\/td>s<\/td>3.33<\/td>CH 2<\/td>67.17<\/td>\n<\/tr>\n
diglyme<\/td>CH 2<\/td>m<\/td>3.43<\/td>CH 2<\/td>72.39<\/td>\n<\/tr>\n
CH 2<\/td>m<\/td>3.31<\/td>CH 2<\/td>70.92<\/td>\n<\/tr>\n
OCH 3<\/td>s<\/td>3.12<\/td>OCH 3<\/td>58.62<\/td>\n<\/tr>\n
DME<\/td>CH 3<\/td>s<\/td>3.12<\/td>CH 3<\/td>58.63<\/td>\n<\/tr>\n
CH 2<\/td>s<\/td>3.31<\/td>CH 2<\/td>72.25<\/td>\n<\/tr>\n
dimethylformamide<\/td>CH<\/td>s<\/td>7.57<\/td>CH<\/td>161.93<\/td>\n<\/tr>\n
CH 3<\/td>s<\/td>2.37<\/td>CH 3<\/td>35.22<\/td>\n<\/tr>\n
CH 3<\/td>s<\/td>1.96<\/td>CH 3<\/td>30.64<\/td>\n<\/tr>\n
ethane<\/td>CH 3<\/td>s<\/td>0.81<\/td>CH 3<\/td>6.94<\/td>\n<\/tr>\n
ethylene<\/td>CH 2<\/td>s<\/td>5.25<\/td>CH 2<\/td>122.92<\/td>\n<\/tr>\n
ethanol<\/td>CH 3<\/td>t<\/td>0.97<\/td>CH 3<\/td>18.78<\/td>\n<\/tr>\n
CH 2<\/td>q<\/td>3.36<\/td>CH 2<\/td>57.81<\/td>\n<\/tr>\n
OH<\/td>s<\/td>0.83<\/td>x<\/td>x<\/td>\n<\/tr>\n
ethylene glycol<\/td>CH 2<\/td>s<\/td>3.36<\/td>CH 2<\/td>64.29<\/td>\n<\/tr>\n
ethyl acetate<\/td>CH3CO<\/td>s<\/td>1.69<\/td>CH3CO<\/td>20.46<\/td>\n<\/tr>\n
<\/td><\/td><\/td>CO<\/td>170.02<\/td>\n<\/tr>\n
C H2 CH3<\/td>q<\/td>3.87<\/td>C H2 CH3<\/td>60.08<\/td>\n<\/tr>\n
CH 2 C H 3<\/td>t<\/td>0.94<\/td>CH 2 C H 3<\/td>14.23<\/td>\n<\/tr>\n
H grease<\/td>CH 3<\/td>m<\/td>0,89-0,96<\/td>x<\/td>x<\/td>\n<\/tr>\n
CH 2<\/td>broad<\/td>1.33<\/td>CH 2<\/td>30.31<\/td>\n<\/tr>\n
hexamethylbenzene<\/td>CH 3<\/td>s<\/td>2.1<\/td>CH 3<\/td>16.84<\/td>\n<\/tr>\n
<\/td><\/td><\/td>C<\/td>131.72<\/td>\n<\/tr>\n
n-hexane<\/td>CH 3<\/td>t<\/td>0.88<\/td>CH 3<\/td>14.34<\/td>\n<\/tr>\n
CH 2<\/td>m<\/td>1.22<\/td>CH 2 (2,5)<\/td>23.12<\/td>\n<\/tr>\n
<\/td><\/td><\/td>CH 2 (3,4)<\/td>32.06<\/td>\n<\/tr>\n
HMDSO<\/td>CH 3<\/td>s<\/td>0.1<\/td>CH 3<\/td>1.99<\/td>\n<\/tr>\n
HMPA<\/td>CH 3<\/td>d<\/td>2.42<\/td>CH 3<\/td>36.8<\/td>\n<\/tr>\n
hydrogen<\/td>H 2<\/td>s<\/td>4.5<\/td>x<\/td>x<\/td>\n<\/tr>\n
imidazole<\/td>CH(2)<\/td>s<\/td>7.3<\/td>CH(2)<\/td>135.57<\/td>\n<\/tr>\n
CH(4,5)<\/td>s<\/td>6.86<\/td>CH(4,5)<\/td>122.13<\/td>\n<\/tr>\n
methane<\/td>CH 4<\/td>s<\/td>0.17<\/td>CH 4<\/td>-4.34<\/td>\n<\/tr>\n
methanol<\/td>CH 3<\/td>s<\/td>3.03<\/td>CH 3<\/td>49.9<\/td>\n<\/tr>\n
OH<\/td>s<\/td><\/td>x<\/td>x<\/td>\n<\/tr>\n
nitromethane<\/td>CH 3<\/td>s<\/td>3.01<\/td>CH 3<\/td>61.14<\/td>\n<\/tr>\n
n-pentane<\/td>CH 3<\/td>t<\/td>0.87<\/td>CH 3<\/td>14.27<\/td>\n<\/tr>\n
CH 2<\/td>m<\/td>1.25<\/td>CH 2 (2,4)<\/td>22.79<\/td>\n<\/tr>\n
<\/td><\/td><\/td>CH 2 (3)<\/td>34.54<\/td>\n<\/tr>\n
propane<\/td>CH 3<\/td>t<\/td>0.89<\/td>CH 3<\/td>16.65<\/td>\n<\/tr>\n
CH 2<\/td>septett<\/td>1.32<\/td>CH 2<\/td>16.63<\/td>\n<\/tr>\n
2-propanol<\/td>CH 3<\/td>d<\/td>0.95<\/td>CH 3<\/td>25.24<\/td>\n<\/tr>\n
CH<\/td>septett<\/td>3.65<\/td>CH<\/td>64.12<\/td>\n<\/tr>\n
propylene<\/td>CH3<\/td>d<\/td>1.55<\/td>CH3<\/td>19.32<\/td>\n<\/tr>\n
CH 2 (1)<\/td>m<\/td>4.92<\/td>CH 2<\/td>115.89<\/td>\n<\/tr>\n
CH 2 (2)<\/td>m<\/td>4.98<\/td>x<\/td>x<\/td>\n<\/tr>\n
CH<\/td>m<\/td>5.7<\/td>CH<\/td>133.61<\/td>\n<\/tr>\n
pyridine<\/td>CH(2,6)<\/td>m<\/td>8.47<\/td>CH(2,6)<\/td>150.25<\/td>\n<\/tr>\n
CH(3,5)<\/td>m<\/td>6.67<\/td>CH(3,5)<\/td>123.46<\/td>\n<\/tr>\n
CH(4)<\/td>m<\/td>6.99<\/td>CH(4)<\/td>135.17<\/td>\n<\/tr>\n
pyrrole<\/td>NH<\/td>broad<\/td>7.71<\/td>x<\/td>x<\/td>\n<\/tr>\n
CH (2,5)<\/td>m<\/td>6.43<\/td>CH (2,5)<\/td>117.61<\/td>\n<\/tr>\n
CH (3,4)<\/td>m<\/td>6.27<\/td>CH (3,4)<\/td>108.15<\/td>\n<\/tr>\n
pyrrolidine<\/td>CH 2 (2,5)<\/td>m<\/td>2.54<\/td>CH 2 (2,5)<\/td>47.12<\/td>\n<\/tr>\n
CH 2 (3,4)<\/td>m<\/td>1.36<\/td>CH 2 (3,4)<\/td>25.75<\/td>\n<\/tr>\n
silicon grease<\/td>CH 3<\/td>s<\/td>0.26<\/td>CH 3<\/td>1.37<\/td>\n<\/tr>\n
tetrahydrofuran<\/td>CH 2 (2,5)<\/td>m<\/td>3.54<\/td>CH 2 (2,5)<\/td>67.75<\/td>\n<\/tr>\n
CH 2 (3,4)<\/td>m<\/td>1.43<\/td>CH 2 (3,4)<\/td>25.79<\/td>\n<\/tr>\n
Toluene<\/td>CH 3<\/td>s<\/td>2.11<\/td>CH 3<\/td>21.37<\/td>\n<\/tr>\n
<\/td><\/td><\/td>C(1)<\/td>137.84<\/td>\n<\/tr>\n
CH (2,4,6)<\/td>m<\/td>6,96-7,01<\/td>CH (2,6)<\/td>129.33<\/td>\n<\/tr>\n
CH (3,5)<\/td>m<\/td>7.09<\/td>CH (3,5)<\/td>128.15<\/td>\n<\/tr>\n
<\/td><\/td><\/td>CH (4)<\/td>125.66<\/td>\n<\/tr>\n
triethylamine<\/td>CH 3<\/td>t<\/td>0.95<\/td>CH 3<\/td>12.39<\/td>\n<\/tr>\n
CH 2<\/td>q<\/td>2.39<\/td>CH 2<\/td>46.82<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\nThe table was taken from German. The comma is therefore the decimal point.
\nFor example, 4.3 stands for the English 4.3.
\n
\nSource:
\nNMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist\t
\nGregory R. Fulmer, Alexander J. M. Miller, Nathaniel H. Sherden, Hugo E. Gottlieb, Abraham Nudelman, Brian M. Stoltz, John E. Bercaw and Karen I. Goldberg\t
\nOrganometallics, 2010, 29 (9), pp 2176\u20132179\t
\nDOI: 10.1021\/om100106e\t<\/span>\n\n","protected":false},"excerpt":{"rendered":"

NMR- data Chemical shift [ppm] (Multiplicity) Coupling constants [Hz] 1H 2.09 (5) 1J(C,D) 22.0 (CD3) 6.97 (H-1) (m) 24.0 (C-2,C-3) 7.09 (H-2) (m) 19.0 (C-4) 7.01 (H-3) 2J(H,D) 2.2 13C 20.4 (7) 125.49 (3) 128.33 (3) 129.24 (3) 137.86 3J(H,D) 1.2 (H-1)  H2O\/HOD Shift  0.45 1.1 (H-2,H-3)   Physical data Formula C7D8 Molecular weight [g\/mol] … <\/p>\n

Continue reading<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"wprm-recipe-roundup-name":"","wprm-recipe-roundup-description":"","jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":false,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2}},"categories":[5,4],"tags":[6],"class_list":["post-49","post","type-post","status-publish","format-standard","hentry","category-nmr","category-spectroscopy","tag-solvent","item-wrap"],"yoast_head":"\nToluene-d8 - Steffen's Chemistry Pages<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Toluene-d8 - Steffen's Chemistry Pages\" \/>\n<meta property=\"og:description\" content=\"NMR- data Chemical shift [ppm] (Multiplicity) Coupling constants [Hz] 1H 2.09 (5) 1J(C,D) 22.0 (CD3) 6.97 (H-1) (m) 24.0 (C-2,C-3) 7.09 (H-2) (m) 19.0 (C-4) 7.01 (H-3) 2J(H,D) 2.2 13C 20.4 (7) 125.49 (3) 128.33 (3) 129.24 (3) 137.86 3J(H,D) 1.2 (H-1)  H2O\/HOD Shift  0.45 1.1 (H-2,H-3)   Physical data Formula C7D8 Molecular weight [g\/mol] … Continue reading\" \/>\n<meta property=\"og:url\" content=\"https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/\" \/>\n<meta property=\"og:site_name\" content=\"Steffen's Chemistry Pages\" \/>\n<meta property=\"article:publisher\" content=\"https:\/\/www.facebook.com\/knowledgeforchemists\" \/>\n<meta property=\"article:author\" content=\"https:\/\/www.facebook.com\/steffen.thomas1\" \/>\n<meta property=\"article:published_time\" content=\"2013-11-06T20:07:20+00:00\" \/>\n<meta property=\"article:modified_time\" content=\"2019-01-20T16:51:58+00:00\" \/>\n<meta property=\"og:image\" content=\"http:\/\/www.science-and-fun.de\/tools\/solvents\/c7d8.gif\" \/>\n<meta name=\"author\" content=\"Steffen\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:creator\" content=\"@steto123\" \/>\n<meta name=\"twitter:site\" content=\"@SienceFun\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"Steffen\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\\\/\\\/schema.org\",\"@graph\":[{\"@type\":\"Article\",\"@id\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/2013\\\/11\\\/06\\\/toluene-d8\\\/#article\",\"isPartOf\":{\"@id\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/2013\\\/11\\\/06\\\/toluene-d8\\\/\"},\"author\":{\"name\":\"Steffen\",\"@id\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/#\\\/schema\\\/person\\\/910dc13be3cb31f39d8707d607e929e8\"},\"headline\":\"Toluene-d8\",\"datePublished\":\"2013-11-06T20:07:20+00:00\",\"dateModified\":\"2019-01-20T16:51:58+00:00\",\"mainEntityOfPage\":{\"@id\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/2013\\\/11\\\/06\\\/toluene-d8\\\/\"},\"wordCount\":92,\"commentCount\":0,\"image\":{\"@id\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/2013\\\/11\\\/06\\\/toluene-d8\\\/#primaryimage\"},\"thumbnailUrl\":\"http:\\\/\\\/www.science-and-fun.de\\\/tools\\\/solvents\\\/c7d8.gif\",\"keywords\":[\"Solvent\"],\"articleSection\":[\"NMR\",\"Spectroscopy\"],\"inLanguage\":\"en-US\",\"potentialAction\":[{\"@type\":\"CommentAction\",\"name\":\"Comment\",\"target\":[\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/2013\\\/11\\\/06\\\/toluene-d8\\\/#respond\"]}]},{\"@type\":\"WebPage\",\"@id\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/2013\\\/11\\\/06\\\/toluene-d8\\\/\",\"url\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/2013\\\/11\\\/06\\\/toluene-d8\\\/\",\"name\":\"Toluene-d8 - Steffen's Chemistry Pages\",\"isPartOf\":{\"@id\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/#website\"},\"primaryImageOfPage\":{\"@id\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/2013\\\/11\\\/06\\\/toluene-d8\\\/#primaryimage\"},\"image\":{\"@id\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/2013\\\/11\\\/06\\\/toluene-d8\\\/#primaryimage\"},\"thumbnailUrl\":\"http:\\\/\\\/www.science-and-fun.de\\\/tools\\\/solvents\\\/c7d8.gif\",\"datePublished\":\"2013-11-06T20:07:20+00:00\",\"dateModified\":\"2019-01-20T16:51:58+00:00\",\"author\":{\"@id\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/#\\\/schema\\\/person\\\/910dc13be3cb31f39d8707d607e929e8\"},\"breadcrumb\":{\"@id\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/2013\\\/11\\\/06\\\/toluene-d8\\\/#breadcrumb\"},\"inLanguage\":\"en-US\",\"potentialAction\":[{\"@type\":\"ReadAction\",\"target\":[\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/2013\\\/11\\\/06\\\/toluene-d8\\\/\"]}]},{\"@type\":\"ImageObject\",\"inLanguage\":\"en-US\",\"@id\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/2013\\\/11\\\/06\\\/toluene-d8\\\/#primaryimage\",\"url\":\"http:\\\/\\\/www.science-and-fun.de\\\/tools\\\/solvents\\\/c7d8.gif\",\"contentUrl\":\"http:\\\/\\\/www.science-and-fun.de\\\/tools\\\/solvents\\\/c7d8.gif\"},{\"@type\":\"BreadcrumbList\",\"@id\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/2013\\\/11\\\/06\\\/toluene-d8\\\/#breadcrumb\",\"itemListElement\":[{\"@type\":\"ListItem\",\"position\":1,\"name\":\"Home\",\"item\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/\"},{\"@type\":\"ListItem\",\"position\":2,\"name\":\"Toluene-d8\"}]},{\"@type\":\"WebSite\",\"@id\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/#website\",\"url\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/\",\"name\":\"Steffen's Chemistry Pages\",\"description\":\"Facts and tables around chemistry\",\"potentialAction\":[{\"@type\":\"SearchAction\",\"target\":{\"@type\":\"EntryPoint\",\"urlTemplate\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/?s={search_term_string}\"},\"query-input\":{\"@type\":\"PropertyValueSpecification\",\"valueRequired\":true,\"valueName\":\"search_term_string\"}}],\"inLanguage\":\"en-US\"},{\"@type\":\"Person\",\"@id\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/#\\\/schema\\\/person\\\/910dc13be3cb31f39d8707d607e929e8\",\"name\":\"Steffen\",\"image\":{\"@type\":\"ImageObject\",\"inLanguage\":\"en-US\",\"@id\":\"https:\\\/\\\/secure.gravatar.com\\\/avatar\\\/6ff13dd29c0d1b8a17460ca74a1e0eee159c14d00728cf5e1a7ee30f8ffdf195?s=96&d=retro&r=g\",\"url\":\"https:\\\/\\\/secure.gravatar.com\\\/avatar\\\/6ff13dd29c0d1b8a17460ca74a1e0eee159c14d00728cf5e1a7ee30f8ffdf195?s=96&d=retro&r=g\",\"contentUrl\":\"https:\\\/\\\/secure.gravatar.com\\\/avatar\\\/6ff13dd29c0d1b8a17460ca74a1e0eee159c14d00728cf5e1a7ee30f8ffdf195?s=96&d=retro&r=g\",\"caption\":\"Steffen\"},\"sameAs\":[\"https:\\\/\\\/sthomas.de\",\"https:\\\/\\\/www.facebook.com\\\/steffen.thomas1\",\"https:\\\/\\\/x.com\\\/steto123\"],\"url\":\"https:\\\/\\\/wissen.science-and-fun.de\\\/chemistry\\\/author\\\/wp_admin\\\/\"}]}<\/script>\n<!-- \/ Yoast SEO plugin. -->","yoast_head_json":{"title":"Toluene-d8 - Steffen's Chemistry Pages","robots":{"index":"index","follow":"follow","max-snippet":"max-snippet:-1","max-image-preview":"max-image-preview:large","max-video-preview":"max-video-preview:-1"},"canonical":"https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/","og_locale":"en_US","og_type":"article","og_title":"Toluene-d8 - Steffen's Chemistry Pages","og_description":"NMR- data Chemical shift [ppm] (Multiplicity) Coupling constants [Hz] 1H 2.09 (5) 1J(C,D) 22.0 (CD3) 6.97 (H-1) (m) 24.0 (C-2,C-3) 7.09 (H-2) (m) 19.0 (C-4) 7.01 (H-3) 2J(H,D) 2.2 13C 20.4 (7) 125.49 (3) 128.33 (3) 129.24 (3) 137.86 3J(H,D) 1.2 (H-1)  H2O\/HOD Shift  0.45 1.1 (H-2,H-3)   Physical data Formula C7D8 Molecular weight [g\/mol] … Continue reading","og_url":"https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/","og_site_name":"Steffen's Chemistry Pages","article_publisher":"https:\/\/www.facebook.com\/knowledgeforchemists","article_author":"https:\/\/www.facebook.com\/steffen.thomas1","article_published_time":"2013-11-06T20:07:20+00:00","article_modified_time":"2019-01-20T16:51:58+00:00","og_image":[{"url":"http:\/\/www.science-and-fun.de\/tools\/solvents\/c7d8.gif","type":"","width":"","height":""}],"author":"Steffen","twitter_card":"summary_large_image","twitter_creator":"@steto123","twitter_site":"@SienceFun","twitter_misc":{"Written by":"Steffen"},"schema":{"@context":"https:\/\/schema.org","@graph":[{"@type":"Article","@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/#article","isPartOf":{"@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/"},"author":{"name":"Steffen","@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/#\/schema\/person\/910dc13be3cb31f39d8707d607e929e8"},"headline":"Toluene-d8","datePublished":"2013-11-06T20:07:20+00:00","dateModified":"2019-01-20T16:51:58+00:00","mainEntityOfPage":{"@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/"},"wordCount":92,"commentCount":0,"image":{"@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/#primaryimage"},"thumbnailUrl":"http:\/\/www.science-and-fun.de\/tools\/solvents\/c7d8.gif","keywords":["Solvent"],"articleSection":["NMR","Spectroscopy"],"inLanguage":"en-US","potentialAction":[{"@type":"CommentAction","name":"Comment","target":["https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/#respond"]}]},{"@type":"WebPage","@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/","url":"https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/","name":"Toluene-d8 - Steffen's Chemistry Pages","isPartOf":{"@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/#website"},"primaryImageOfPage":{"@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/#primaryimage"},"image":{"@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/#primaryimage"},"thumbnailUrl":"http:\/\/www.science-and-fun.de\/tools\/solvents\/c7d8.gif","datePublished":"2013-11-06T20:07:20+00:00","dateModified":"2019-01-20T16:51:58+00:00","author":{"@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/#\/schema\/person\/910dc13be3cb31f39d8707d607e929e8"},"breadcrumb":{"@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/#breadcrumb"},"inLanguage":"en-US","potentialAction":[{"@type":"ReadAction","target":["https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/"]}]},{"@type":"ImageObject","inLanguage":"en-US","@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/#primaryimage","url":"http:\/\/www.science-and-fun.de\/tools\/solvents\/c7d8.gif","contentUrl":"http:\/\/www.science-and-fun.de\/tools\/solvents\/c7d8.gif"},{"@type":"BreadcrumbList","@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/06\/toluene-d8\/#breadcrumb","itemListElement":[{"@type":"ListItem","position":1,"name":"Home","item":"https:\/\/wissen.science-and-fun.de\/chemistry\/"},{"@type":"ListItem","position":2,"name":"Toluene-d8"}]},{"@type":"WebSite","@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/#website","url":"https:\/\/wissen.science-and-fun.de\/chemistry\/","name":"Steffen's Chemistry Pages","description":"Facts and tables around chemistry","potentialAction":[{"@type":"SearchAction","target":{"@type":"EntryPoint","urlTemplate":"https:\/\/wissen.science-and-fun.de\/chemistry\/?s={search_term_string}"},"query-input":{"@type":"PropertyValueSpecification","valueRequired":true,"valueName":"search_term_string"}}],"inLanguage":"en-US"},{"@type":"Person","@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/#\/schema\/person\/910dc13be3cb31f39d8707d607e929e8","name":"Steffen","image":{"@type":"ImageObject","inLanguage":"en-US","@id":"https:\/\/secure.gravatar.com\/avatar\/6ff13dd29c0d1b8a17460ca74a1e0eee159c14d00728cf5e1a7ee30f8ffdf195?s=96&d=retro&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/6ff13dd29c0d1b8a17460ca74a1e0eee159c14d00728cf5e1a7ee30f8ffdf195?s=96&d=retro&r=g","contentUrl":"https:\/\/secure.gravatar.com\/avatar\/6ff13dd29c0d1b8a17460ca74a1e0eee159c14d00728cf5e1a7ee30f8ffdf195?s=96&d=retro&r=g","caption":"Steffen"},"sameAs":["https:\/\/sthomas.de","https:\/\/www.facebook.com\/steffen.thomas1","https:\/\/x.com\/steto123"],"url":"https:\/\/wissen.science-and-fun.de\/chemistry\/author\/wp_admin\/"}]}},"jetpack_publicize_connections":[],"jetpack_featured_media_url":"","jetpack_shortlink":"https:\/\/wp.me\/p5ltLS-N","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/posts\/49","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/comments?post=49"}],"version-history":[{"count":3,"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/posts\/49\/revisions"}],"predecessor-version":[{"id":1693,"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/posts\/49\/revisions\/1693"}],"wp:attachment":[{"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/media?parent=49"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/categories?post=49"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/tags?post=49"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}