{"id":1540,"date":"2017-04-08T16:21:16","date_gmt":"2017-04-08T14:21:16","guid":{"rendered":"https:\/\/wissen.science-and-fun.de\/chemistry\/?p=1540"},"modified":"2017-04-29T10:43:00","modified_gmt":"2017-04-29T08:43:00","slug":"cysteine-cys-c","status":"publish","type":"post","link":"https:\/\/wissen.science-and-fun.de\/chemistry\/2017\/04\/08\/cysteine-cys-c\/","title":{"rendered":"Cysteine (Cys, C)"},"content":{"rendered":"<h3>NMR-Data [1] of Cysteine:<\/h3>\n<table border=\"1\">\n<tbody>\n<tr>\n<th rowspan=\"11\"><img data-recalc-dims=\"1\" loading=\"lazy\" decoding=\"async\" class=\"alignleft size-full wp-image-5994\" src=\"https:\/\/i0.wp.com\/wissen.science-and-fun.de\/wp-content\/uploads\/2014\/01\/cystein.png?resize=125%2C109&#038;ssl=1\" alt=\"Cystein\" width=\"125\" height=\"109\" \/><\/th>\n<th rowspan=\"2\" valign=\"top\">Atom<\/th>\n<th rowspan=\"2\" valign=\"top\">Atomtyp<\/th>\n<th colspan=\"3\">chemical\u00a0shift [ppm]<sup>1<\/sup><\/th>\n<th rowspan=\"2\">Random Coil<br \/>\nchem. shift\u00a0<sup>3<\/sup><\/th>\n<th rowspan=\"2\">Random Coil<br \/>\nchem. shift\u00a0<sup>4<\/sup><\/th>\n<\/tr>\n<tr>\n<td><strong>average<\/strong><\/td>\n<td><strong>standard deviation<\/strong><\/td>\n<td><strong>entries<sup>2<\/sup><\/strong><\/td>\n<\/tr>\n<tr>\n<td>H<\/td>\n<td>H<\/td>\n<td>8.378<\/td>\n<td>\u00a00.70<\/td>\n<td>\u00a017331<\/td>\n<td>\u00a08.32 (red.)<br \/>\n8.43 (ox.)<\/td>\n<td>\u00a08.30 (red.)<\/td>\n<\/tr>\n<tr>\n<td>H\u03b1<\/td>\n<td>H<\/td>\n<td>4.685<\/td>\n<td>\u00a01.068<\/td>\n<td>\u00a015042<\/td>\n<td>\u00a04.55 (red.)<br \/>\n4.71 (ox.)<\/td>\n<td>\u00a04.81 (red.)<\/td>\n<\/tr>\n<tr>\n<td>H\u03b22<\/td>\n<td>H<\/td>\n<td>3.188<\/td>\n<td>\u00a07.196<\/td>\n<td>\u00a014553<\/td>\n<td>\u00a02.93 (red.)<br \/>\n3.25 (ox.)<\/td>\n<td>\u00a02.93 (red.)<\/td>\n<\/tr>\n<tr>\n<td>H\u03b23<\/td>\n<td>H<\/td>\n<td>3.104<\/td>\n<td>\u00a06.522<\/td>\n<td>\u00a014186<\/td>\n<td>\u00a02.93 (red.)<br \/>\n2.99 (ox.)<\/td>\n<td>\u00a02.85 (red.)<\/td>\n<\/tr>\n<tr>\n<td>H\u03b3<\/td>\n<td>H<\/td>\n<td>2.099<\/td>\n<td>\u00a01.47<\/td>\n<td>\u00a0166<\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td>C<\/td>\n<td>C<\/td>\n<td>174.843<\/td>\n<td>\u00a03.529<\/td>\n<td>\u00a08181<\/td>\n<td>\u00a0174.6 (red.)<br \/>\n174.6 (ox.)<\/td>\n<td>\u00a0173.0 (red.)<\/td>\n<\/tr>\n<tr>\n<td>C\u03b1<\/td>\n<td>C<\/td>\n<td>58.107<\/td>\n<td>\u00a03.403<\/td>\n<td>\u00a011954<\/td>\n<td>\u00a058.2 (red.)<br \/>\n55.4 (ox.)<\/td>\n<td>\u00a056.4 (red.)<\/td>\n<\/tr>\n<tr>\n<td>C\u03b2<\/td>\n<td>C<\/td>\n<td>33.117<\/td>\n<td>\u00a06.348<\/td>\n<td>\u00a011347<\/td>\n<td>\u00a028.0 (red.)<br \/>\n41.1 (ox.)<\/td>\n<td>\u00a027.1 (red.)<\/td>\n<\/tr>\n<tr>\n<td>N<\/td>\n<td>N<\/td>\n<td>120.563<\/td>\n<td>\u00a021.65<\/td>\n<td>\u00a013164<\/td>\n<td>\u00a0118.8 (red.)<br \/>\n118.6 (ox.)<\/td>\n<td>\u00a0119.9 (red.)<\/td>\n<\/tr>\n<tr>\n<th>proportion of proteines<\/th>\n<th colspan=\"2\">pK<sub>2<\/sub> COOH<\/th>\n<th>pK<sub>1<\/sub>COOH<\/th>\n<th colspan=\"2\">isoelectrical point<\/th>\n<th>pK<sub>1<\/sub>NH<sub>2<\/sub><\/th>\n<th>pK<sub>2<\/sub>NH<sub>2<\/sub><\/th>\n<\/tr>\n<tr>\n<td>\u00a02.8%<\/td>\n<td colspan=\"2\">\u00a08.33 (-SH)<\/td>\n<td>\u00a01.71<\/td>\n<td colspan=\"2\">\u00a05.05<\/td>\n<td>\u00a010.78<\/td>\n<td>\u00a0&#8211;<\/td>\n<\/tr>\n<tr>\n<th>CAS- Nummer<\/th>\n<th colspan=\"2\">molar mass<\/th>\n<th>formula<\/th>\n<th colspan=\"2\">density<\/th>\n<th>melting point<\/th>\n<th>solubility<\/th>\n<\/tr>\n<tr>\n<td>\n<ul>\n<li>52-90-4 (<small>L<\/small>-Enantiomer)<\/li>\n<li>921-01-7 (<small>D<\/small>-Enantiomer)<\/li>\n<li>3374-22-9 (<small>DL<\/small>-Cysteine)<\/li>\n<li>52-89-1 (<small>L<\/small>-Cysteine\u00b7Hydrochlorid)<\/li>\n<li>3374-22-9 (<small>DL<\/small>-Cysteine)<\/li>\n<li>207121-46-8 (<small>D<\/small>-Cysteine\u00b7Hydrochlorid\u00b7Monohydrat)<\/li>\n<li>7048-04-6 (<small>L<\/small>-Cystein\u00b7Hydrochloride\u00b7Monohydrat)<\/li>\n<\/ul>\n<\/td>\n<td colspan=\"2\">\u00a0121,16 g\u00b7mol<sup>\u22121<\/sup><\/td>\n<td>\u00a0C<sub>3<\/sub>H<sub>7<\/sub>NO<sub>2<\/sub>S<\/td>\n<td colspan=\"2\"><\/td>\n<td>\u00a0220\u2013228 \u00b0C<\/td>\n<td>\n<ul>\n<li>good\u00a0in water: 280\u00a0g\u00b7l<sup>\u22121<\/sup>(20\u00a0\u00b0C)\u00a0<sup id=\"cite_ref-Merck_1-2\"><a href=\"http:\/\/de.wikipedia.org\/wiki\/Cystein#cite_note-Merck-1\"><br \/>\n<\/a><\/sup><\/li>\n<li>good in alcohol, acetic acid, not in ether and benzole<sup id=\"cite_ref-R.C3.B6mpp_3-0\"><a href=\"http:\/\/de.wikipedia.org\/wiki\/Cystein#cite_note-R.C3.B6mpp-3\"><br \/>\n<\/a><\/sup><\/li>\n<\/ul>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<hr \/>\n<p><sup>1<\/sup> Depending on the type of atom it was <sup>1<\/sup>H, <sup>13<\/sup>C or <sup>15<\/sup>N chemical shift. <sup>1<\/sup>H und <sup>13<\/sup>C relative to TMS and <sup>15<\/sup>N relative to liquid ammonia<\/p>\n<p><sup>2<\/sup> Number of individual chemical shift data for averaging according to [2]<\/p>\n<p><sup>3<\/sup> with Alanine as neighborhood in the hexapeptide Gly-Gly-X-Ala-Gly-Gly [3]<\/p>\n<p><sup>4<\/sup> with Proline as neighborhood in the hexapeptide Gly-Gly-X-Pro-Gly-Gly [3]<\/p>\n<hr>\n<h3>3D- Modell<\/h3>\n<div style=\"height: 400px; width: 400px; border-style: solid; position: relative;\" class='viewer_3Dmoljs' data-href='https:\/\/wissen.science-and-fun.de\/molekel\/cystein.sdf' data-backgroundcolor='0xffffff' data-style='stick' data-typ='sdf'><\/div>\n<p><\/p>\n<p>sources:<\/p>\n<p>[1] &#8220;BioMagResBank&#8221;, Eldon L. Ulrich; Hideo Akutsu; Jurgen F. Doreleijers; Yoko Harano; Yannis E. Ioannidis; Jundong Lin; Miron Livny; Steve Mading; Dimitri Maziuk; Zachary Miller; Eiichi Nakatani; Christopher F. Schulte; David E. Tolmie; R. Kent Wenger; Hongyang Yao; John L. Markley; Nucleic Acids Research 36, D402-D408 (2008) doi: 10.1093\/nar\/gkm957<\/p>\n<p>[2] http:\/\/www.bmrb.wisc.edu\/ last visit march 2017<\/p>\n<p>[3] David S. Wishart, Colin G. Bigam, Arne Holm, Robert S. Hodges, Brian D. Sykes; Journal of Biomolecular NMR<br \/>\nJanuary 1995, Volume 5, Issue 1, pp 67-81 doi:10.1007\/BF00227471<\/p>\n<p>[4] Wikipedia\u00a0http:\/\/de.wikipedia.org\/wiki\/Aminos%C3%A4uren (last visit january 2014)<\/p>\n<p>[5] Wikipedia http:\/\/de.wikipedia.org\/wiki\/Asparagin\u00a0(last visit january 2014)<\/p>\n<p>3D Mol: Nicholas Rego and David Koes<br \/>\n3Dmol.js: molecular visualization with WebGL<br \/>\nBioinformatics (2015) 31 (8): 1322-1324 doi:10.1093\/bioinformatics\/btu829<\/p>\n","protected":false},"excerpt":{"rendered":"<p>NMR-Data [1] of Cysteine: Atom Atomtyp chemical\u00a0shift [ppm]1 Random Coil chem. shift\u00a03 Random Coil chem. shift\u00a04 average standard deviation entries2 H H 8.378 \u00a00.70 \u00a017331 \u00a08.32 (red.) 8.43 (ox.) \u00a08.30 (red.) H\u03b1 H 4.685 \u00a01.068 \u00a015042 \u00a04.55 (red.) 4.71 (ox.) \u00a04.81 (red.) H\u03b22 H 3.188 \u00a07.196 \u00a014553 \u00a02.93 (red.) 3.25 (ox.) \u00a02.93 (red.) H\u03b23 H &hellip; <\/p>\n<p><a class=\"more-link btn\" href=\"https:\/\/wissen.science-and-fun.de\/chemistry\/2017\/04\/08\/cysteine-cys-c\/\">Continue reading<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"wprm-recipe-roundup-name":"","wprm-recipe-roundup-description":"","jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2}},"categories":[5,4],"tags":[98,104,99],"class_list":["post-1540","post","type-post","status-publish","format-standard","hentry","category-nmr","category-spectroscopy","tag-bio-nmr","tag-cysteine","tag-nmr","item-wrap"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.3 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Cysteine (Cys, C) - Steffen&#039;s Chemistry Pages<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/wissen.science-and-fun.de\/chemistry\/2017\/04\/08\/cysteine-cys-c\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Cysteine (Cys, C) - Steffen&#039;s Chemistry Pages\" \/>\n<meta property=\"og:description\" content=\"NMR-Data [1] of Cysteine: Atom Atomtyp chemical\u00a0shift [ppm]1 Random Coil chem. shift\u00a03 Random Coil chem. shift\u00a04 average standard deviation entries2 H H 8.378 \u00a00.70 \u00a017331 \u00a08.32 (red.) 8.43 (ox.) \u00a08.30 (red.) 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H\u03b1 H 4.685 \u00a01.068 \u00a015042 \u00a04.55 (red.) 4.71 (ox.) \u00a04.81 (red.) H\u03b22 H 3.188 \u00a07.196 \u00a014553 \u00a02.93 (red.) 3.25 (ox.) \u00a02.93 (red.) 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