{"id":140,"date":"2013-11-10T13:06:27","date_gmt":"2013-11-10T11:06:27","guid":{"rendered":"https:\/\/wissen.science-and-fun.de\/chemistry\/?p=140"},"modified":"2013-12-13T07:10:37","modified_gmt":"2013-12-13T05:10:37","slug":"phosphorous","status":"publish","type":"post","link":"https:\/\/wissen.science-and-fun.de\/chemistry\/2013\/11\/10\/phosphorous\/","title":{"rendered":"Phosphorous"},"content":{"rendered":"

NMR- Data<\/h2>\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
Isotope<\/td>\n\u00a031<\/sup>P<\/td>\nNatural abundance (%)<\/td>\n\u00a0100<\/td>\n<\/tr>\n
Spin<\/td>\n1\/2<\/td>\nMagnetic moment \u03bc\/\u03bcN<\/sub><\/td>\n\u00a01.95999<\/td>\n<\/tr>\n
Magnetogyric ratio
\n\u03b3\/107<\/sup>rad s-1<\/sup>T-1<\/sup><\/td>\n		\u00a010.8394<\/td>\nFrequency ratio
\n\u039e\/%<\/td>\n		\u00a040.480742<\/td>\n<\/tr>\n
Reference Compound<\/td>\n\u00a0H3<\/sub>PO4<\/sub><\/td>\nSample conditions<\/td>\n<\/td>\n<\/tr>\n
receptivity relative to 1<\/sup>H<\/td>\n\u00a06.65*10-2<\/sup><\/td>\nreceptivity relative to 13<\/sup>C<\/td>\n\u00a03.91*102<\/sup><\/td>\n<\/tr>\n
Larmor Frequenzies (MHZ) vs. Bruker Field Strengths (Tesla<\/span>)<\/th>\n<\/tr>\n
7.04925<\/td>\n9.39798<\/td>\n11.7467<\/td>\n14.0954<\/td>\n<\/tr>\n
\u00a0121.495<\/td>\n\u00a0161.976<\/td>\n\u00a0202.457<\/td>\n\u00a0242.938<\/td>\n<\/tr>\n
16.4442<\/td>\n17.6185<\/td>\n18.7929<\/td>\n19.9673<\/td>\n<\/tr>\n
\u00a0283.419<\/td>\n\u00a0303.659<\/td>\n\u00a0323.900<\/td>\n\u00a0344.140<\/td>\n<\/tr>\n
21.1416<\/td>\n22.3160<\/td>\n23.4904<\/td>\n<\/td>\n<\/tr>\n
\u00a0364.380<\/td>\n\u00a0384.621<\/td>\n\u00a0404.861<\/td>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
\n\n\n\n\n\t\n\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t\n\t
Phosphorus (III) compounds<\/th>\n<\/tr>\n<\/thead>\n
<\/td>δ \/ ppm<\/td><\/td>δ \/ppm<\/td>\n<\/tr>\n
PMe3<\/sub><\/td>-62<\/td>PMeF2<\/sub><\/td>245<\/td>\n<\/tr>\n
PEt3<\/sub><\/td>-20<\/td>PMeH2<\/sub><\/td>-163.5<\/td>\n<\/tr>\n
P(n-Pr)3<\/sub><\/td>-33<\/td>PMeCl2<\/sub><\/td>192<\/td>\n<\/tr>\n
P(i-Pr)3<\/sub><\/td>-19.4<\/td>PMeBr2<\/sub><\/td>184<\/td>\n<\/tr>\n
P(n-Bu)3<\/sub><\/td>-32.5<\/td>PMe2<\/sub>F<\/td>186<\/td>\n<\/tr>\n
P(i-Bu)3<\/sub><\/td>-45.3<\/td>PMe2<\/sub>H<\/td>-99<\/td>\n<\/tr>\n
P(s-Bu)3<\/sub><\/td>7.9<\/td>PMe2<\/sub>Cl<\/td>96.5<\/td>\n<\/tr>\n
P(t-Bu)3<\/sub><\/td>63<\/td>PMe2<\/sub>Br<\/td>90.5<\/td>\n<\/tr>\n
Phosphorous (V) compounds<\/td>\n<\/tr>\n
Me3<\/sub>PO<\/td>36.2<\/td>Me3<\/sub>PS<\/td>59.1<\/td>\n<\/tr>\n
Et3<\/sub>PO<\/td>48.3<\/td>Et3<\/sub>PS<\/td>54.5<\/td>\n<\/tr>\n
[Me4<\/sub>P]+<\/sup><\/td>24.4<\/td>[Et 4<\/sub>P]+<\/sup><\/td>40.1<\/td>\n<\/tr>\n
[PO4<\/sub>]3-<\/sup><\/td>6.0<\/td>[PS<\/sub>]3-<\/sup><\/td>87<\/td>\n<\/tr>\n
PF5<\/sub><\/td>-80.3<\/td>[PF6<\/sub>]-<\/sup><\/td>-145<\/td>\n<\/tr>\n
PCl5<\/sub><\/td>-80<\/td>[PCl4<\/sub>]+<\/sup><\/td>86<\/td>\n<\/tr>\n
MePF4<\/sub><\/td>-29.9<\/td>[PCl6<\/sub>]-<\/sup><\/td>-295<\/td>\n<\/tr>\n
Me3<\/sub>PF2<\/sub><\/td>-158<\/td>Me2<\/sub>PF3<\/sub><\/td>8.0<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\nChemical shifts relativ to 85% H3<\/sub>PO4<\/sub><\/span>\n\n","protected":false},"excerpt":{"rendered":"

NMR- Data Isotope \u00a031P Natural abundance (%) \u00a0100 Spin 1\/2 Magnetic moment \u03bc\/\u03bcN \u00a01.95999 Magnetogyric ratio \u03b3\/107rad s-1T-1 \u00a010.8394 Frequency ratio \u039e\/% \u00a040.480742 Reference Compound \u00a0H3PO4 Sample conditions receptivity relative to 1H \u00a06.65*10-2 receptivity relative to 13C \u00a03.91*102 Larmor Frequenzies (MHZ) vs. Bruker Field Strengths (Tesla) 7.04925 9.39798 11.7467 14.0954 \u00a0121.495 \u00a0161.976 \u00a0202.457 \u00a0242.938 16.4442 … <\/p>\n

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