{"id":24,"date":"2013-11-04T21:08:59","date_gmt":"2013-11-04T19:08:59","guid":{"rendered":"https:\/\/wissen.science-and-fun.de\/chemistry\/?page_id=24"},"modified":"2013-11-04T21:08:59","modified_gmt":"2013-11-04T19:08:59","slug":"27al-chemical-shifts","status":"publish","type":"page","link":"https:\/\/wissen.science-and-fun.de\/chemistry\/spectroscopy\/27al-chemical-shifts\/","title":{"rendered":"27Al chemical shifts"},"content":{"rendered":"<h4><sup>27<\/sup>Al chemical shifts<\/h4>\n<p>Al(H<sub>2<\/sub>O)<sub>6<\/sub><sup>3+<\/sup> = 0 ppm<\/p>\n<p>All chemical shifts given in ppm!<\/p>\n<p>Source: Bruker Almanac 2012<\/p>\n<table>\n<tbody>\n<tr>\n<th>Type<\/th>\n<th>chemical shift range<\/th>\n<\/tr>\n<tr>\n<td>alkyls, hydrides and their adducts<\/td>\n<td>65 to 220<\/td>\n<\/tr>\n<tr id=\"ld\">\n<td>halides and AlX<sub>4<\/sub><sup>&#8211;<\/sup><\/td>\n<td>-30 to 90<\/td>\n<\/tr>\n<tr>\n<td>halide adducts with O- donor ligands<\/td>\n<td>85 to 105<\/td>\n<\/tr>\n<tr id=\"ld\">\n<td>halide adducts with P- donor ligands<\/td>\n<td>85 to 110<\/td>\n<\/tr>\n<tr>\n<td>alkoxides and their adducts<\/td>\n<td>60 to 120<\/td>\n<\/tr>\n<tr id=\"ld\">\n<td>tetrahedral AlO<sub>4<\/sub> coordination<\/td>\n<td>55 to 80<\/td>\n<\/tr>\n<tr>\n<td>Octahedral AlO<sub>6<\/sub> in hydrates, hydroxides, aluminates, zeolites<\/td>\n<td>-15 to 10<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n","protected":false},"excerpt":{"rendered":"<p>27Al chemical shifts Al(H2O)63+ = 0 ppm All chemical shifts given in ppm! Source: Bruker Almanac 2012 Type chemical shift range alkyls, hydrides and their adducts 65 to 220 halides and AlX4&#8211; -30 to 90 halide adducts with O- donor ligands 85 to 105 halide adducts with P- donor ligands 85 to 110 alkoxides and &hellip; <\/p>\n<p><a class=\"more-link btn\" href=\"https:\/\/wissen.science-and-fun.de\/chemistry\/spectroscopy\/27al-chemical-shifts\/\">Continue reading<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"parent":7,"menu_order":8,"comment_status":"open","ping_status":"open","template":"","meta":{"wprm-recipe-roundup-name":"","wprm-recipe-roundup-description":"","footnotes":""},"class_list":["post-24","page","type-page","status-publish","hentry","nodate","item-wrap"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.6 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>27Al chemical shifts - Steffen&#039;s Chemistry Pages<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/wissen.science-and-fun.de\/chemistry\/spectroscopy\/27al-chemical-shifts\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"27Al chemical shifts - Steffen&#039;s Chemistry Pages\" \/>\n<meta property=\"og:description\" content=\"27Al chemical shifts Al(H2O)63+ = 0 ppm All chemical shifts given in ppm! 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Source: Bruker Almanac 2012 Type chemical shift range alkyls, hydrides and their adducts 65 to 220 halides and AlX4&#8211; -30 to 90 halide adducts with O- donor ligands 85 to 105 halide adducts with P- donor ligands 85 to 110 alkoxides and &hellip; Continue reading","og_url":"https:\/\/wissen.science-and-fun.de\/chemistry\/spectroscopy\/27al-chemical-shifts\/","og_site_name":"Steffen&#039;s Chemistry Pages","article_publisher":"https:\/\/www.facebook.com\/knowledgeforchemists","twitter_card":"summary_large_image","twitter_site":"@SienceFun","schema":{"@context":"https:\/\/schema.org","@graph":[{"@type":"WebPage","@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/spectroscopy\/27al-chemical-shifts\/","url":"https:\/\/wissen.science-and-fun.de\/chemistry\/spectroscopy\/27al-chemical-shifts\/","name":"27Al chemical shifts - Steffen&#039;s Chemistry Pages","isPartOf":{"@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/#website"},"datePublished":"2013-11-04T19:08:59+00:00","breadcrumb":{"@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/spectroscopy\/27al-chemical-shifts\/#breadcrumb"},"inLanguage":"en-US","potentialAction":[{"@type":"ReadAction","target":["https:\/\/wissen.science-and-fun.de\/chemistry\/spectroscopy\/27al-chemical-shifts\/"]}]},{"@type":"BreadcrumbList","@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/spectroscopy\/27al-chemical-shifts\/#breadcrumb","itemListElement":[{"@type":"ListItem","position":1,"name":"Home","item":"https:\/\/wissen.science-and-fun.de\/chemistry\/"},{"@type":"ListItem","position":2,"name":"Spectroscopy","item":"https:\/\/wissen.science-and-fun.de\/chemistry\/spectroscopy\/"},{"@type":"ListItem","position":3,"name":"27Al chemical shifts"}]},{"@type":"WebSite","@id":"https:\/\/wissen.science-and-fun.de\/chemistry\/#website","url":"https:\/\/wissen.science-and-fun.de\/chemistry\/","name":"Steffen&#039;s Chemistry Pages","description":"Facts and tables around chemistry","potentialAction":[{"@type":"SearchAction","target":{"@type":"EntryPoint","urlTemplate":"https:\/\/wissen.science-and-fun.de\/chemistry\/?s={search_term_string}"},"query-input":{"@type":"PropertyValueSpecification","valueRequired":true,"valueName":"search_term_string"}}],"inLanguage":"en-US"}]}},"jetpack_shortlink":"https:\/\/wp.me\/P5ltLS-o","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/pages\/24","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/comments?post=24"}],"version-history":[{"count":1,"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/pages\/24\/revisions"}],"predecessor-version":[{"id":25,"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/pages\/24\/revisions\/25"}],"up":[{"embeddable":true,"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/pages\/7"}],"wp:attachment":[{"href":"https:\/\/wissen.science-and-fun.de\/chemistry\/wp-json\/wp\/v2\/media?parent=24"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}